Note: In lieu of an abstract, this is the article's first page. Click to increase image size Free first page. View: PDF. Related Content. View: PDF | PDF w/ Links. Related Content. Related Content: Advanced Inorganic Chemistry, 6th Edition (Cotton, F. A.; Wilkinson, G.; Murillo, C. A.; Bochmann, M.) Journal of Inorganic chemistry: principles of structure and reactivity, 4th ed. Library of Congress Cataloging in Publication Data: Advanced inorganic chemistry. -6th ed. / by F. Albert Cotton, Geoffrey Wilkinson, Carlos A. Murillo, and .
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Cotton, Frank Albert, Advanced inorganic chemistry. “A Wiley-Interscience publication." Includes index. 1. Chemistry, Inorganic. I, Wilkinson,. Geoffrey. ADVANCED. INORGANIC. CHEMISTRY. A Comprehensive Text. F. ALBERT COTTON. ROBERT A. WELCH PROFESSOR OF CHEMISTRY. TEXAS A AND M . View: PDF Advanced Inorganic Chemistry, 6th Edition (Cotton, F. A.; Wilkinson, G.; Murillo, Inorganic chemistry: principles of structure and reactivity, 4th ed.
Sc and Y in group 3 are also generally recognized as transition metals. However, the elements La—Lu and Ac—Lr and group 12 attract different definitions from different authors. Many chemistry textbooks and printed periodic tables classify La and Ac as group 3 elements and transition metals, since their atomic ground-state configurations are s2d1 like Sc and Y. Some inorganic chemistry textbooks include La with the lanthanides and Ac with the actinides. The group 12 elements Zn, Cd and Hg may therefore, under certain criteria, be classed as post-transition metals in this case. However, it is often convenient to include these elements in a discussion of the transition elements. Another example occurs in the Irving—Williams series of stability constants of complexes.
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Some of these cross-cutting topics are further developed in later chapters on transition metal chemistry. The bulk of the book Parts 2 and 3 then covers the periodic table systematically. Apart from the increase in authors each contribute to about one-fourth of the contents other changes have been made to the book since the fifth edition.
For example, the chapter on boron chemistry has been rewritten by Russell Grimes and some of the broad topical chapters e. Bioinorganic Chemistry and Organometallic Compounds have been removed and the topics dealt with on an element to element basis. In its arrangement of material the sixth edition is therefore more similar to the third edition than the fourth or fifth editions though it is, as expected, more comprehensive.
Recent theoretical advances in the interpretation of structure, bonding and reactivity in inorganic compounds are covered as can be seen by the incorporation of refreshingly up-to-date references, which are given as footnotes to most pages and at the end of each chapter. All molecular diagrams, tables and equations are clearly presented. This book, which is reasonably priced, will no doubt become a recommended text for many university chemistry courses.
It is both comprehensive and authoritative and provides a wealth of information in inorganic chemistry for both the student and the professional chemist.